$re = '/(^.+?(?=(__|_FF|_SS|_TT|_FS|_SF)))/m';
$str = 'CALOUT_DFE_0__FFGNP_0P9VDD_0P72VDDA_0C_Cbest
rxdetout_SSGNP_1P05VDD_0P88VDDA_M40C_Cworst';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php