$re = '/(?:AND|OR|SUB|ADD)\([^()]+\)(?:\[SET\([^()]+\))?\[?COIL\(Seq\[\d+\]\.(?:Seq|Bool)\[\d+\]\.\d+/m';
$str = 'AND(Seq[1].Mat)AND(Type_G012.WithData)[COIL(Seq[1].Bool[93].11),XIC(Seq[1].exp)RES(Seq[1].ita)]
AND(Seq[1].Mat)AND(Type_G014.WithData)AND(Type_G015.WithData)[SET(zzSeq[1].WaitStep)COIL(Seq[1].Seq[93].10),AND(Seq[1].exp)RES(Seq[1].ita)]';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php