$re = '/(?: \/ |\A)((?:(?! \/ )[^:])+):/';
$str = 'Lorem: 8 FB / Ipsum-/Dolor: Some Text / Dolor: Some text with (brackets) / Sit amet.:
Some Text with/slash / foobar / Last one: 36 foos';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php