$re = '/(\\\\\\\\([0-9]{1,3}\.[0-9]{1,3}\.[0-9]{1,3}\.[0-9]{1,3})\\\\[-a-zA-Z_ 0-9]+\\\\)(?:[-a-zA-Z_ 0-9\.]+\\\\)*/m';
$str = '\\\\192.168.0.250\\Volume1_public\\21 - THW Test Rig\\Automation\\Results\\05 - 717 Official Rig\\7 - Nitya\\717 - Realistic Test v0.1 For SC v2.02.00 onwards Isolated CopyLogs Test.txt\\13012023_8\\';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php