$re = '/&(?!(?:apos|quot|[gl]t|amp);|#)/';
$str = '<field>& is escaped</field>
<field>"also escaped"</field>
<field>is & "not" escaped</field>
<field>is " and is not & escaped</field>';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php