$re = '/(?!file:)(\w+.img)/m';
$str = 'disk = [file:/OVS/Repositories/0004fb0000030000df2ee11376f1cd94/VirtualDisks/b7558d7745c14b02806d08f8003906e1.img,xvda,w,phy:/OVS/Repositories/0004fb0000030000df2ee11376f1cd94/VirtualDisks/0004fb0000120000049ec392e534e039,xvdb,w,file:/OVS/Repositories/0004fb0000030000df2ee11376f1cd94/VirtualDisks/0004fb0000120000843bb7e2fe395f24.img,xvdc,w]
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php