$re = '/IVR\/\d{8}\/(M{0,4}(?:CM|CD|D?C{0,3})(?:XC|XL|L?X{0,3})(?:IX|IV|V?I{0,3}))\/(M{0,4}(?:CM|CD|D?C{0,3})(?:XC|XL|L?X{0,3})(?:IX|IV|V?I{0,3}))\/(\d{7,9})/';
$str = 'your invoice number IVR/20170531/XVII/V/12652967 and IVR/20170531/XVII/V/13652967';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php