$re = '/(\[\{[^\{\[\]\}]*)(\",\")([^\[\]\{\}]*\}\])/m';
$str = '{"action":"add","actions":[{"country","IND"}],"ctx":"{\\"charset\\":\\"UTF-8\\",\\"client_id\\":\\"G9.2.2045341156.1629864410\\",\\"cookie\\":\\"1\\",\\"domain_user\\":\\"28f51979-bef8-4731-b242-e3a00496d9ba\\",\\"fp\\":\\"659810303\\",\\"id\\":\\"d368f505-6226-4650-aeba-caf9fb18fc53\\",\\"page_res\\":\\"478x4952\\",\\"refr\\"
Sample records';
$subst = "\1\\\",\\\"\3";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php