$re = '/^(?!.*Tag4).*\/Group1\/.*/m';
$str = '/Group1/Tag1
/Group1/Tag2
/Group1/Tag3
/Group1/GroupVoltage/Tag1
/Group1/GroupVoltage/Tag2
/Group1/GroupVoltage/Tag3
/Group1/GroupVoltage/Tag4
/Group2/Tag1
/Group2/Tag2
/Group2/Tag3
/Group2/GroupVoltage/Tag1
/Group2/GroupVoltage/Tag2
/Group2/GroupVoltage/Tag3
/Group2/GroupVoltage/Tag4
/Group3/Tag1
/Group3/Tag2
/Group3/Tag3
/Group3/GroupVoltage/Tag1
/Group3/GroupVoltage/Tag2
/Group3/GroupVoltage/Tag3
/Group3/GroupVoltage/Tag4
/Group4/Tag1
/Group4/Tag2
/Group4/Tag3
/Group4/GroupVoltage/Tag1
/Group4/GroupVoltage/Tag2
/Group4/GroupVoltage/Tag3
/Group4/GroupVoltage/Tag4';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php