$re = '/(?<!Call\(Name\(\')\b\w+\b(?=\', Load)/';
$str = 'Module([Assign([Name(\'a\', Store())], Num(2)), Assign([Name(\'b\', Store())], Num(3)), Assign([Name(\'c\', Store())], Str(\'Hello\')), Assign([Name(\'x\', Store())], BinOp(Name(\'a\', Load()), Add(), Name(\'b\', Load()))), Assign([Name(\'x\', Store())], Name(\'a\', Load())), Expr(Call(Name(\'print\', Load()), [Name(\'a\', Load())], [], None, None)), For(Name(\'i\', Store()), Call(Name(\'range\', Load()), [Num(10)], [], None, None), [Expr(Call(Name(\'print\', Load()), [Name(\'a\', Load())], [], None, None))], [])])';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php