$re = '/(?<=^|\s)(?:\w?\'?)(@(\S+))/m';
$str = '1. take this -> @Mark
2. take this -> @mark_2
3. take this -> @中国
4. take this -> l\'@antro
5. don\'t take this -> 中国@中国.zh
6. don\'t take this -> 中国@google.zh
7. don\'t take this -> info@google.com
8. don\'t take this -> 99@test.com';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php