$re = '/\s*on\s*(?!.*on)/im';
$str = 'Syed on Arafath on Jan 7, 2015
Capt.KSD on Dec 30, 2014
chakradharalasakani on Dec 29, 2014
mitesh0123 on Dec 18, 2014
Aparajita61@yahoo.in on Dec 3, 2014
123chetan on Oct 28, 2014';
$subst = "\n";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php