$re = '/^(?:(?!(?:0[1]|1[3-7]):\d\d:\d\d).)*((?:0[1]|1[3-7]):\d\d:\d\d)/m';
$str = 'Received: by 127.0.0.1 with SMTP id co5csp22954317qdb; Wed, 6 May 2015 13:02:22 -0700 (PDT) X-Received: by 127.0.0.1 with SMTP id j185mr26699743oig.68.1430928141923; Wed, 06 May 2015 13:02:21 -0700 (PDT)';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php