$re = '/(?<!(?:\\\\{2})*\\\\)(?:(?<begin_capture>[\(])(?:(?=[<][a-z_A-Z]+[>])|(?!\?(?:<?[=!]|:)))|(?<begin_non_capture>\((?=\?(?:<?[=!]|:))))|(?:(?<end>\)))/m';
$str = '// Basic - All standard capture groups
(?<=^[ \\t]*)(//)([ ])(?<capture_name>)(Case:)([ \\t]+)(.*\\S)([ \\t]*)?$
// Complex
(?<=^[ \\t]*)(//)([ ])(Case:)([ \\t]+)(.*\\S)([ \\t]*)?$';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php