$re = '/Start\W+([0-9]{2})/m';
$str = '\'\\ufeffStore :,RS1 FAC_RS1 (South) ,Cashier :,2079 : Holly,Terminal :,2 : POS2 ,Receipt Number :,59450,Invoice Number :,RS102059450,Start :,01/01/2016 06:35:23 AM,End : ,01/01/2016 06:35:23 AM\\nItem ID,Receipt Alias,Quantity Sold,Unit Price,Extended Price,,,,,,,,,\',
\'Store :,RS1 FAC_RS1 (South) ,Cashier :,2138 : Mark,Terminal :,4 : POS4 ,Receipt Number :,59234,Invoice Number :,RS104059234,Start :,01/01/2016 06:41:41 AM,End : ,01/01/2016 06:41:41 AM\\nItem ID,Receipt Alias,Quantity Sold,Unit Price,Extended Price,,,,,,,,,\',
\'Store :,RS1 FAC_RS1 (South) ,Cashier :,2138 : Mark,Terminal :,3 : POS3 ,Receipt Number :,64407,Invoice Number :,RS103064407,Start :,01/01/2016 06:43:54 AM,End : ,01/01/2016 06:43:54 AM\\nItem ID,Receipt Alias,Quantity Sold,Unit Price,Extended Price,,,,,,,,,\',
\'Store :,RS1 FAC_RS1 (South) ,Cashier :,2138 : Mark,Terminal :,5 : POS5 ,Receipt Number :,64806,Invoice Number :,RS105064806,Start :,01/01/2016 06:46:21 AM,End : ,01/01/2016 06:46:21 AM\\nItem ID,Receipt Alias,Quantity Sold,Unit Price,Extended Price,,,,,,,,,\',
\'Store :,RS1 FAC_RS1 (South) ,Cashier :,1618 : Aron,Terminal :,6 : POS6 ,Receipt Number :,67963,Invoice Number :,RS106067963,Start :,01/01/2016 06:56:34 AM,End : ,01/01/2016 06:56:34 AM\\nItem ID,Receipt Alias,Quantity Sold,Unit Price,Extended Price,,,,,,,,,\',
\'Store :,RS1 FAC_RS1 (South) ,Cashier :,1618 : Aron,Terminal :,6 : POS6 ,Receipt Number :,67964,Invoice Number :,RS106067964,Start :,01/01/2016 07:20:35 AM,End : ,01/01/2016 07:21:04 AM\\nItem ID,Receipt Alias,Quantity Sold,Unit Price,Extended Price,,,,,,,,,\\n668,FA BRKFST WRAP,2.000,$2.99,$5.98,,,,,,,,,\\n102,COFFEE 12 OZ,1.000,$1.50,$1.50,,,,,,,,,\',
\'Store :,RS1 FAC_RS1 (South) ,Cashier :,1618 : Aron,Terminal :,6 : POS6 ,Receipt Number :,67964,Invoice Number :,RS106067964,Start :,01/01/2016 07:20:35 AM,End : ,01/01/2016 07:21:04 AM\\nItem ID,Receipt Alias,Quantity Sold,Unit Price,Extended Price,,,,,,,,,\\n,SUBTOTAL,,,$7.48,,,,,,,,,\\n,TOTAL,,,$7.48,,,,,,,,,\\n,TOTAL ';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php