$re = '/(\d+)(?!.*\b\1\b)/';
$str = '[[8,9,7],[7,8,9,33,21],[11,12,33,21,9,31]]';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php