$re = '/^([a-zA-Z]+ \d{1,2} \d{1,2}:\d{1,2}:\d{1,2})|([^ ]+)=([^ ]+)/m';
$str = 'Aug 13 17:16:33 app-srv01 kernel: newConnection - IN=eth0 OUT= MAC=56:00:01:a1:5c:b7:fe:00:01:a1:5c:b7:08:00 SRC=91.103.125.80 DST=45.33.223.166 LEN=52 TOS=0x00 PREC=0x00 TTL=113 ID=21200 DF PROTO=TCP SPT=55743 DPT=445 WINDOW=8192 RES=0x00 SYN URGP=0
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php