$re = '/(?<=\d\s,\s)(?!.*\d\s,\s).*/m';
$str = 'Step=10 , Step=11 , Step=12 , Step=13 , Step=14 , Step=15 , Step=16 , Step=18 , Step=17 , Step=20 , Step=19 , Step=25 , Step=21 , Step=26 , Step=28 , Step=24 , Step=22 , Step=23 , Step=27 , Step=30 , Step=29 , Step=35 , Step=34 , Step=32 , Step=31 , Step=38 , Step=37 , Step=36 , Step=50 , Step=45 , Step=48 , Step=41 , Step=52 , Step=42 , Step=57 , Step=65 , Step=61 , Step=62 , Step=64 , Step=54 , Step=53 , Step=59 , Step=63 , Step=84 , Step=71 , SelectedAuthenticationIdentityStores=paddedvalue, NetworkDeviceName=exampledevice, NetworkDeviceGroups=Update Source:All Sources:ACS, NetworkDeviceGroups=Device Type:All Device Types:Wireless, NetworkDeviceGroups=Location:All Locations, ServiceSelectionMatchedRule=Rule-1, IdentityPolicyMatchedRule=Default';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php