$re = '/^((?:.+\n)*?.*(?:(HARRY)(?:(?!\n\n)(?:.|\n))*?(DIVISION)).*(?:\n.+)*)$/m';
$str = 'S3007/0011
20150590824
HARRY MOSES
F
32
DIVISION 4
CIV-\'F\' HIST-\'D\' GEO-\'F\' KISW-\'D\' ENGL-\'D\' PHY-\'F\' CHEM-\'F\' BIO-\'F\' B/MATH-\'F\'
S3007/0012
20151514797
HARRY MORGAN
F
26
DIVISION 3
CIV-\'D\' HIST-\'C\' GEO-\'D\' KISW-\'C\' ENGL-\'C\' PHY-\'F\' CHEM-\'F\' BIO-\'D\' B/MATH-\'F\'
S3007/0012
20151514797
DIVISION MORGAN
F
26
HARRY 3
CIV-\'D\' HIST-\'C\' GEO-\'D\' KISW-\'C\' ENGL-\'C\' PHY-\'F\' CHEM-\'F\' BIO-\'D\' B/MATH-\'F\'
S3007/0013
20151514798
HAPPINESS DEOGRATIAS
F
34
DIVISION 0
CIV-\'F\' HIST-\'F\' GEO-\'F\' KISW-\'D\' ENGL-\'F\' PHY-\'F\' CHEM-\'F\' BIO-\'F\' B/MATH-\'F';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php