$re = '/("|\s)(?<key>(CN|C|O|OU|S))=(?<value>[^=\"]+)(?=(\s|"))/';
$str = 'ssl_issuer="CN=DigiCert SHA2 High Assurance Server CA C=US O=DigiCert Inc OU=www.digicert.com" ssl_hash="f41565b049f039e765a0f8be8271a4b4817b7378" ssl_subject="CN=syndication.twitter.com C=US S=California O=Twitter, Inc. OU=Twitter Security" ssl_start_time="Wed Jun 29 00:00:00 2016 UTC" ssl_end_time="Mon Sep 16 12:00:00 2019 UTC" ssl_type="X.509 Certificate" ssl_extended_key_usage="Server Authentication, Client Authentication" ssl_key_length="2048 bits" ssl_key_usage="Digital Signature, Key Encipherment"
ssl_subject="CN=*.eu-west-1.webrootcloudav.com" ssl_start_time="Tue Aug 22 00:00:00 2017 UTC" ssl_end_time="Sat Sep 22 12:00:00 2018 UTC" ssl_type="X.509 Certificate" ssl_extended_key_usage="" ssl_key_length="2048 bits" ssl_key_usage="Digital Signature, Non-Repudiation, Key Encipherment"
ssl_subject="CN=*.us.static.hrsmart.com C=US S=Virginia O=Deltek, Inc. OU=Security Services" ssl_start_time="Thu Jan 11 00:00:00 2018 UTC" ssl_end_time="Sun Mar 31 12:00:00 2019 UTC" ssl_type="X.509 Certificate" ssl_extended_key_usage="Server Authentication, Client Authentication" ssl_key_length="2048 bits" ssl_key_usage="Digital Signature, Key Encipherment"
ssl_subject="CN=*.googleapis.com C=US S=California O=Google Inc" ssl_start_time="Tue Mar 13 18:57:10 2018 UTC" ssl_end_time="Tue Jun 5 18:17:00 2018 UTC" ssl_type="X.509 Certificate" ssl_extended_key_usage="Server Authentication, Client Authentication" ssl_key_length="0 bits" ssl_key_usage="Digital Signature, Certificate Signing, CRL Signing"
ssl_subject="CN=subscription.rhsm.redhat.com C=US S=North Carolina O=Red Hat, Inc. OU=Red Hat Network" ssl_start_time="Thu May 18 16:30:24 2017 UTC" ssl_end_time="Sat May 18 16:30:24 2019 UTC" ssl_type="X.509 Certificate" ssl_extended_key_usage="Server Authentication" ssl_key_length="4096 bits" ssl_key_usage=""';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php