$re = '/Temp:(.+?),/m';
$str = 'Temp:C5E501374D0343090957F7E5929E765C931F7D3EC7A96189FDA88549D54D9E4E5DB3FC1C2, adfsafd1242412,';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php