$re = '/\b(?<label>[a-z0-9_]\w*)\s?(?<selector>=~?|![=~])\s?"?(?<value>(?<=")(?:[^\\\\"]|\\\\.)*(?=")|\w+[^\s},]+)/mi';
$str = '{quote =~ "She said: \\"Hi, all!( How\'re you…)?\\"", quote=~some_value}';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php