$re = '/^(?:(?!@2=[^@]*@3=B3(?:[@>]|$)).)*@2=([^@]*)@3=B3(?:[@>]|$)(?!.*@2=(?!\1)[^@]*@3=B3(?:[@>]|$))/m';
$str = '@1=A1@2=A2@3=A3>>@1=B1@2=B2@3=B3>>@1=C1@2=B2@3=C3>>@1=B1@2=B2@3=B3
@1=A1@2=A2@3=A3>>@1=B1@2=B2@3=B3>>@1=C1@2=B2@3=C3>>@1=B1@2=ABC@3=B3
@1=A1@2=A2@3=A3>>@1=B1@2=B2@3=B3>>@1=C1@2=B2@3=C3';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php