$re = '/_(.*?)(?=\\\\)/';
$str = '{\\"header\\":[[{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"text\\",\\"text\\":\\"<p>Opportunity<\\\\/p>\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"text\\",\\"text\\":\\"<p>Date<\\\\/p>\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"text\\",\\"text\\":\\"<p>Launch Vehicle<\\\\/p>\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"text\\",\\"text\\":\\"<p>Excess Capacity<\\\\/p>\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"text\\",\\"text\\":\\"<p>Orbit<\\\\/p>\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"text\\",\\"text\\":\\"<p>Cost<\\\\/p>\\",\\"type\\":\\"Paragraph\\"}]}]],\\"style\\":\\"normal\\",\\"body\\":[[{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"reference\\",\\"sourceProperty\\":\\"name\\",\\"source\\":\\"_18_0_2_f280366_1447380313181_755886_144674\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"reference\\",\\"sourceProperty\\":\\"value\\",\\"source\\":\\"_18_0_2_f280366_1447380432770_58741_154478\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"reference\\",\\"sourceProperty\\":\\"value\\",\\"source\\":\\"_18_0_2_f280366_1447380396246_873072_144853\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"reference\\",\\"sourceProperty\\":\\"value\\",\\"source\\":\\"_18_0_2_f280366_1447380432768_736282_154472\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"reference\\",\\"sourceProperty\\":\\"value\\",\\"source\\":\\"_18_0_2_f280366_1447380395593_804641_144677\\",\\"type\\":\\"Paragraph\\"}]},{\\"colspan\\":\\"1\\",\\"rowspan\\":\\"1\\",\\"content\\":[{\\"sourceType\\":\\"reference\\",\\"sourceProperty\\":\\"value\\",\\"source\\":\\"_18_0_2_f280366_1447380433550_448862_154654\\",\\"type\\":\\"Paragraph\\"}]}]],\\"title\\":\\"Possible Rideshares\\",\\"type\\":\\"Table\\"}
IShouldGet3Match,allTheSequenceBetweenaUnderScoreAndASlashHere\'sOne:_1234_1234\\andheresAnother_1234_1234_1234\\OhLookAnotherOne!_123_12_1234567\\bahbahba
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php