$re = '/^(?!.*(second|minute|hour|day|week|month|year).*\1)\d+\s+(?:second|minute|hour|day|week|month|year)s?(?: +\d+\s+(?:second|minute|hour|day|week|month|year)s?)*$/mi';
$str = '2 days
3 years
12 hours
2 days 6 hours 30 minutes
4352 YEARS 2 weeks 4 days 5 days 2 minutes 30 second
2 days 12 hours 6 hours 2 minutes';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php