$re = '/To:( =\?.*\?= )(Cc|Subject):/m';
$str = '# Base base
To: =?GB2312?B?s8LR9A==?= , =?GB2312?B?0e7V8buq?= , =?GB2312?B?ts69qNOi?= , =?GB2312?B?wO7RxcX0?= , =?GB2312?B?wfXX07vU?= Cc: =?GB2312?B?wfXA2g==?= , =?GB2312?B?wfW7qNHT?= Subject: =?GB2312?B?u9i4tDogu9i4tDogcGPXqNawvNK9zMrTxrVidWc=?=
# Base base without Cc:
To: =?GB2312?B?s8LR9A==?= , =?GB2312?B?0e7V8buq?= , =?GB2312?B?ts69qNOi?= , =?GB2312?B?wO7RxcX0?= , =?GB2312?B?wfXX07vU?= Subject: =?GB2312?B?u9i4tDogu9i4tDogcGPXqNawvNK9zMrTxrVidWc=?=
# Only one addressee
To: =?GB2312?B?s8LR9A==?= Cc: =?GB2312?B?wfXA2g==?= , =?GB2312?B?wfW7qNHT?= Subject: =?GB2312?B?u9i4tDogu9i4tDogcGPXqNawvNK9zMrTxrVidWc=?=
# Only one addressee without Cc:
To: =?GB2312?B?s8LR9A==?= Subject: =?GB2312?B?u9i4tDogu9i4tDogcGPXqNawvNK9zMrTxrVidWc=?=
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php