$re = '/(")""|"/m';
$str = '"StackOverflow"
"""StackOverflow"""
"""""StackOverflow""""" five quotes remain as one quote
""""""StackOverflow"""""" six quotes become two quotes';
$subst = "\1";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php