$re = '/(?!^)(?=\[\d{2}])/m';
$str = '[01] Final Step - Protonica [02] Liquid Frequencies (Liquid Soul Mix) - Liquid Soul [03] Global Illumination - Liquid Soul [04] Devotion - Liquid Soul [05] Black Rock City - Quantize [06] Plazza Del Trripy - Andromeda [07] Private Guide - Suntree [08] Stereo Gun - Vibrasphere [09] The Cycle - Ritree [10] Atmonizer - Andromed';
$subst = "\n";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php