$re = '/<<\[(\w+)\]>>/';
$str = 'Label: Code <<[RecLetCode]>>
Label: <<[RecResponseDate]>>: <<[RecResponseMemo]>>
Label: <<[ResponseDate]>><br><<[DateResponseDue]>><br><<[EstCompleteDate]>> 
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php