$re = '/^.* \[client x.x.x.x\] (?!client denied by server configuration:.*\/app\/etc\/local\.xml).*$/m';
$str = '[Fri Oct 18 17:39:11 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 17:39:38 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 17:39:44 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/mariapiacasa.com.br/app/etc/local.xml
[Fri Oct 18 17:42:41 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 17:47:33 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 17:47:49 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 17:47:58 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 17:50:02 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 17:59:37 2013] [error] [client x.x.x.x] client denied by server configuration: /home/client/client.com.br/app/etc/local.xml
[Fri Oct 18 19:05:34 2013] [error] [client x.x.x.x] File does not exist: /home/client/client.com.br/skin/frontend/default/MAG080138';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php