$re = '/^(?!\d\d\s-\s\d\d).*/m';
$str = '01 - 10
This is the first one :1
02 - 20
This is the second one -2
03 - 30
This is the third one "3
04 - 40
This is the forth one ;4
05 - 50
This is the fifth one .5';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php