$re = '/(\s)\w+\=/i';
$str = 'module=SCM fa=PP at=SCM.PP.GENERATE si=E02F07592081B6A58F7FFC3DE035D62B ci=JShenSCM cn=GRIFOLS, S.A. cs=SCM_JShenSCM. pi=dbPool1 ui=new_user_id locale=en_US ktf1=[EM,EX,EH] if1=2950 ktf3=3x3 ktf4=TEAMVIEW ktf5=MYSELF ktf6=ALL ktf8=[gender,department,division,location] if2=0 if3=1 if4=0
module=SCM fa=PP at=SCM.PP.GENERATE si=E02F07592081B6A58F7FFC3DE035D62B ci=JShenSCM cn=Deutsche Telekom AG cs=SCM_JShenSCM. pi=dbPool1 ui=new_user_id locale=en_US ktf1=[] if1=2950 ktf3=3x3 ktf4=TEAMVIEW ktf5=MYSELF ktf6=ALL ktf8=[gender,department,division,location] if2=0 if3=1 if4=0
module=SCM fa=PP at=SCM.PP.GENERATE si=E02F07592081B6A58F7FFC3DE035D62B ci=JShenSCM cn=Deutsche Bank cs=SCM_JShenSCM. pi=dbPool1 ui=new_user_id locale=en_US ktf1=[EM,EX,EMM] if1=2950 ktf3=3x3 ktf4=TEAMVIEW ktf5=MYSELF ktf6=ALL ktf8=[] if2=0 if3=1 if4=0
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php