$re = '/(\d.+)(?=\s*\" Unit=\"W\" Type=\"AC_Power\")/m';
$str = '<Measurements>
<Measurement Value="237.6" Unit="V" Type="AC_Voltage"/>
<Measurement Value="9.828" Unit="A" Type="AC_Current"/>
<Measurement Value="2344.7" Unit="W" Type="AC_Power"/>
<Measurement Value="2343.4" Unit="W" Type="AC_Power_fast"/>
<Measurement Value="50.003" Unit="Hz" Type="AC_Frequency"/>
<Measurement Value="294.4" Unit="V" Type="DC_Voltage1"/>
<Measurement Value="171.3" Unit="V" Type="DC_Voltage2"/>
<Measurement Value="8.056" Unit="A" Type="DC_Current1"/>
<Measurement Unit="A" Type="DC_Current2"/>
<Measurement Value="343.8" Unit="V" Type="LINK_Voltage"/>
<Measurement Unit="W" Type="GridPower"/>
<Measurement Unit="W" Type="GridConsumedPower"/>
<Measurement Unit="W" Type="GridInjectedPower"/>
<Measurement Unit="W" Type="OwnConsumedPower"/>
<Measurement Value="100.0" Unit="%" Type="Derating"/>
</Measurements>
</Device>
</root>';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php