$re = '/(?P<keys>\d+)\s*(?:=\s*)?(?P<values>.*?)(?=\s*(?:,\s*)?(?:\d|\Z))/m';
$str = 'Value names: 0 = Something, 1 = Something, else, 4 = A value, 5 = BAD - enough, 6 GOOD, 7 = Ugly,';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php