$re = '/([\w-]+): (.+?)\\\\r\\\\n(?:([^:]+?)\\\\r\\\\n)?/';
$str = 'MIME-Version: 1.0\\r\\n
x-no-auto-attachment: 1\\r\\n
Received: by 10.200.36.132; Sun, 5 Feb 2017 01:21:33 -0800 (PST)\\r\\n
Date: Sun, 5 Feb 2017 01:21:33 -0800\\r\\n
Message-ID: <IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII@mail.gmail.com>\\r\\n
Subject: =?UTF-8?Q?MMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMM?=\\r\\n
=?UTF-8?Q?ail?=\\r\\n \\
From: =?UTF-8?B?VGhlIGZ1Y2sgYXJlIHUgbG9va2luZyBmb3I/?= <noreply@mail.com>\\r\\n
To: mail mail <mail@mail.com>\\r\\n
Content-Type: multipart/alternative; boundary=1a3xca651sv561fd321c5xv61sd12\\r\\n
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php