$re = '/([^@,;\s]+@[^@,;\s]+)|(?:$|\s*[,;])(?:\s*)(.*?)<([^@,;\s]+@[^@,;\s]+)>/';
$str = 'name@domain.com,Sixpack, Joe 1 <name@domain.com>, Sixpack, Joe 2 <name@domain.com> ;Sixpack, Joe, 3<name@domain.com> , nameFoo@domain.com,nameBar@domain.com;nameBaz@domain.com;';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php