$re = '/^(?:\s*\d+\s+Secs\s*\(\s*(\d+(?:\.\d+)?%)\)){3}/m';
$str = '5 Secs ( 22.3463%) 60 Secs ( 25.677%) 300 Secs ( 21.3522%)
5 Secs ( 13.6713%) 60 Secs ( 15.3520%) 300 Secs ( 15.9640%)';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php