$re = '/(?<=;Password=)(?:(?!;[\w ]+=).)*/i';
$str = 'add key="myKey" value="Data Source=MyDataSource;Initial Catalog=MyDB;User ID=test-user;Password=pA&-pass; unicode=True"
add key="myKey" value="Data Source=MyDataSource;Initial Catalog=MyDB;User ID=test-user;Password=pass>; unicode=True"';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php