$re = '/^([^\h]+)\h*(?:(OPS|EC5|CSP|PBF|PVF)(?:([^\h])\h|([^\h]{2})|\h{2}))(?:([^\h]{2})|\h{2})\h([^\h]+)\h+(.{4})\h(.{5})\h(.{10})\h/m';
$str = '7089 OPS 7089 1 / aar both all
7901 OPS 7901 1 / aar both all
90510 EC500 467012312312345 3 / ars both all
906101PVFMC46 701234567 12/ ars both all
90-71011CSP 46 707123457 12/ ars both all ';
$subst = "$1|$2$3$4|$5|$6|$7|$8|$9|";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php