$re = '/[ ^\s]([ ]{1,})[ ^\s]/miU';
$str = '5382948 EGELSTON^ELIZABETH 0102126763 1942-09-17 00:00:00.000 F 2003-02-09 00:00:00.000 1899-12-30 19:39:10.000 CT03011350 28465 1.2.124.113532.10.7.222.5.20030209.190851.3087742 NULL UNKNOWN^RADNET CT NULL PE CHEST 764A NULL BODY Northwestern Memorial Hosp. NMH5_OC0 NULL NULL NULL 4 467 544 NULL 2003-04-27 22:56:55.000 NULL 2003-04-27 23:14:42.000 8 2009-06-07 09:22:07.640 2015-11-14 03:54:07.407 2015-11-14 03:54:08.290 NULL NULL CT NULL 5706865 5382948 CT 1.2.840.113619.2.55.1.1762864829.1989.1044811980.588.5 5 Recon 2: ROUTINE PE NULL 5.7 ROUTINE PE NULL 1.2.124.113532.10.7.222.5.20030209.190851.3087742.9814.0.12 4 200 NULL NULL NULL 8 NULL NULL NULL 7276786 5706865 3 NULL 4 NULL 0102126763\\1_2_124_113532_10_7_222_5_\\7276786.0 NULL 289158 NULL 3 ASP_NMH_99_LIB2 \\\\asp1nsx02\\ASP_NMH_99_LIB2\\Incoming \\\\asp1nsx02\\ASP_NMH_99_LIB2\\Images LOCAL';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php