$re = '/Available Times:\s*(?<available>.*?)\s+Other type of contact:\s*(?<contact>.*?)\s+Unavailable Times:\s*(?<unavailable>.*?)\s*$/';
$str = ' Available Times: Monday Tuesday Wednesday 8-12 12-5 Other type of contact: SMS Unavailable Times: Thursday 8-12 ';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php