$re = '/(?<=\bconnectionString=")[^"]*/m';
$str = '<connectionStrings>
<add name="FrameworkEntities" connectionString="metadata=res://*/PortalEntities.csdl|res://*/PortalEntities.ssdl|res://*/PortalEntities.msl;provider=System.Data.SqlClient;
provider connection string="data source=someservername.domain.co;initial catalog=Portal;persist security info=True;user
id=user;password=user$ecurity;MultipleActiveResultSets=True;App=EntityFramework;" providerName="System.Data.EntityClient" />
</connectionStrings>
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php