$re = '/(?=\*LABEL).\w+\s[“]\w+.[-]?.\w+[”]/m';
$str = '*QUESTION 99924 *ALPHA 1026L3 *DUMMY *VAR “version” *LABEL “SCRIPT VERSION” *PROPERTIES “ReportType=IsShell;ExcludeFromDAU=True”
*QUESTION 270 *CODES 4705L996 *RANDOM *MULTI *MIN 1 *LABEL “BARRIERS_TO_ATTENDENCE - B3” *VAR “BARRIERS_TO_ATTENDENCE” *PROPERTIES “DIMVAR=BARRIERS_TO_ATTENDENCE” *IF [#Q180,1] UIOPTIONS "? ROWPICKER"
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php