$re = '/((\\\\\\\\.*\\\\.*|.*\\\\)([{]?[0-9A-Fa-f]{8}-[0-9A-Fa-f]{4}-[0-9A-Fa-f]{4}-[0-9A-Fa-f]{4}-[0-9A-Fa-f]{12}[}])?\.(exe|scr|cpl|bat|js|cmd|vbs).*)/m';
$str = '\\\\localhost\\ADMIN$\\Temp\\RayVentoryPortal\\ndtrack\\mgsreservice.exe';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php