$re = '/(?<!\)),/';
$str = '(40.959953710949506, -74.18210638344726),(40.95891663745299, -74.10606039345703),(40.917472246121065, -74.09582940498359),(40.921752754230255, -74.16397897163398),(40.95248644043785, -74.21067086616523)';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php