$re = '/tcp\h.*?:80\h.*?\busers:\(\("\K[^"]+(?=")/m';
$str = 'tcp LISTEN 0 10 0.0.0.0:80 0.0.0.0:* users:(("nc",pid=3474,fd=4))
tcp LISTEN 0 10 [::]:80 [::]:* users:(("nc",pid=3474,fd=3))
tcp LISTEN 0 511 *:80 *:* users:(("apache2",pid=6741,fd=4),("apache2",pid=6740,fd=4),("apache2",pid=6738,fd=4),("apache2",pid=6737,fd=4),("apache2",pid=6736,fd=4),("apache2",pid=6724,fd=4))
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php