$re = '/href=[\'\"]?([^\'\" >]+)/';
$str = '"<li><a>href=http://w...content-available-to-author-only...f.br/cdara/sisu-2/sisu-2017-1a-edicao/lista-de-espera-sisu-3/?id_curso=01GV&id_grupo=70>ADMINISTRAÇÃO - GOVERNADOR VALADARES - DIURNO - SISU - GRUPO A</a></li><li><a href=http://w...content-available-to-author-only...f.br/cdara/sisu-2/sisu-2017-1a-edicao/lista-de-espera-sisu-3/?id_curso=01GV&id_grupo=71>ADMINISTRAÇÃO - GOVERNADOR VALADARES - DIURNO - SISU - GRUPO B</a></li>"';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php