$re = '/>> ([a-zA-Z ]+)(?=:)/m';
$str = '>> John doe: Hello, I am John Doe. >> Hello, I am Jane Doe. >> Thank you for coming, we will start in two minutes. >> Sam Smith: [no audio] Good morning, everyone.';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php