$re = '/\bStandard Deviation:\h+\K\d[\d.]*/m';
$str = '  Format: JPEG (Joint Photographic Experts Group JFIF format)
  Geometry: 934x1189
  Class: DirectClass
  Type: true color
  Depth: 8 bits-per-pixel component
  Channel Depths:
    Red:      8 bits
    Green:    8 bits
    Blue:     8 bits
  Channel Statistics:
    Red:
      Minimum:                  3855.00 (0.0588)
      Maximum:                 65535.00 (1.0000)
      Mean:                    44325.84 (0.6764)
      Standard Deviation:       8571.68 (0.1308)
    Green:
      Minimum:                     0.00 (0.0000)
      Maximum:                 65021.00 (0.9922)
      Mean:                    38079.03 (0.5810)
      Standard Deviation:       8109.29 (0.1237)
    Blue:
      Minimum:                     0.00 (0.0000)
      Maximum:                 61423.00 (0.9373)
      Mean:                    31937.17 (0.4873)
      Standard Deviation:       8422.80 (0.1285)
  Resolution: 72x72 pixels/inch
  Filesize: 101.3Ki
  Interlace: No
  Orientation: Unknown
  Background Color: white
  Border Color: #DFDFDF
  Matte Color: #BDBDBD
  Page geometry: 934x1189+0+0
  Compose: Over
  Dispose: Undefined
  Iterations: 0
  Compression: JPEG
  JPEG-Quality: 70
  JPEG-Colorspace: 2
  JPEG-Colorspace-Name: RGB
  JPEG-Sampling-factors: 2x2,1x1,1x1
  Signature: 68c70dc2aacc49610538d037e7913f66945d7655bb4acc83fa5e13c3581016a9
  Profile-color: 456 bytes
  Tainted: False
  Elapsed Time: 0m:0.006050s
  Pixels Per Second: 175.0Mi';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php