$re = '/<(?\'ins_libl\'.*?)><(?\'apt_nom\'.*?)><(?\'apt_telephone\'.*?)><(?\'tsy_lib\'.*?)><(?\'qsy_lib\'.*?)><(?\'num_externe\'.*?)><(?\'apt_localisation\'.*?)><(?\'urg_cd\'.*?)><(?\'commentaire_externe\'.*?)>/m';
$str = ' <Bari Via Adolfo Omodeo 49/a><DELLINO,SARA><+393484546557><Serramenti (porte, finestre, ecc)><Serramenti (porte, finestre, ecc)><41798><P2,torre ovest><3b-><Ciao, la porta del locale pulizie dell\'open space torre ovest non presenta la griglia metallica. possiamo ripristinarla? Grazie Sara>';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php